Stabilisation of mercury during Bayer process digestion

Mercury is introduced into the Bayer refining process as a trace element in bauxite. During the digestion stage, a portion of the mercury is extracted which partitions between the flash tank off-gas, vapour condensate and bauxite residue streams. A technology or treatment that stabilises mercury in the solid phase during digestion would prevent environmental management issues that may arise from the presence of mercury in condensate and non-condensable gases. This study examines the effect of process additives on the deportment of mercury under Bayer digestion conditions. Bauxite digestion experiments were conducted in batch autoclaves in the presence of additives. Process liquor was analysed for mercury content using a thermal desorption technique. Pyrite and copper hydroxide were evaluated for their suitability as additives.