Tailoring Crystal Facets of Metal–Organic Layers to Enhance Photocatalytic Activity for CO2 Reduction
2020
It is common that different crystal facets in metal and metal oxide nanocrystals display different catalytic performances, whereas such phenomena have been rarely documented in metal-organic frameworks (MOFs). Herein, we demonstrate for the first time that a nickel metal-organic layer (MOL) exposing rich (100) crystal facets ( Ni-MOL-100 ) shows a much higher photocatalytic CO 2 -to-CO activity than the one exposing rich ( 010 ) crystal facets ( Ni-MOL-010 ) and its bulky counterpart (bulky Ni-MOF ), with a catalytic activity up to 2.5 and 4.6 times more active than Ni-MOL-010 and bulky Ni-MOF, respectively. Theoretical studies reveal that the two coordination-unsaturated Ni(II) ions with a close distance of 3.50 A on the surface of Ni-MOL-100 enables synergistic catalysis , leading to more favorable energetics in CO 2 reduction than that of Ni-MOL-010.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
38
References
32
Citations
NaN
KQI