Hierarchical Self-Assembly of Conjugated Block Copolymers and Semiconducting Nanorods into One-Dimensional Nanocomposites

Semiconducting organic–inorganic nanocomposites comprising conjugated polymers (CPs) and semiconducting nanocrystals (NCs) represent an important class of functional materials. The ability to organize CPs and NCs into self-assembled nanostructures in close proximity may enable efficient charge or energy transfer between them for use in flexible electronics, light-emitting displays, and photovoltaics. Herein we report the crafting of one-dimensional (1D) functional nanocomposites composed of all-conjugated diblock copolymers and CdSe nanorods (NRs) via two consecutive self-assembly processes, namely, self-assembly of poly(3-hexylselenophene)-block-poly(3-butylselenophene) (denoted P3HS-b-P3BS) diblock copolymers into nanofibers, followed by self-assembly of P3HS-b-P3BS nanofibers and CdSe NRs to yield P3HS-b-P3BS–CdSe NR nanocomposites. Notably, P3HS-b-P3BS diblock copolymers are first rationally designed and synthesized, exhibiting a narrow optical bandgap and forming nanofibers due to strong interchain π...