Molecular Metallophosphate Precursors for NonhydrolyticTransformations
2010
We prepared molecular aluminum, titanium, and zirconium
alkoxide phosphates as precursors for the nonhydrolytic
condensation routes and for thermolytic methods. Syntheses
included the reactions between derivates of phosphoric acid
OP(OSiMe3)3 and OP(OSiMe3)2(OH) and metalloorganic compounds,
such as metal alkyls and alkoxides. The single-crystal X-ray
diffraction analysis was used to establish the molecular
structures of precursors. Their complete characterization was
carried out by analytical and spectroscopic methods (NMR, IR,
MS). The prepared compounds served as molecular precursors to
metallophosphate materials.
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