Comparison of hydrogen production and system performance in a microbial electrolysis cell containing cathodes made of non-platinum catalysts and binders

Abstract Microbial electrolysis cell (MEC) is an innovative electrochemical technology that decomposes organic matter in anode and produces hydrogen in cathode. It is imperative to use a high-performance and a low-cost cathode material to make the application of MEC economically viable. In this study, five different cathodes made of low-cost materials were tested in MECs. The materials included activated carbon (AC) and nickel powder (Ni) as a cathode catalyst; polytetrafluoroethylene (PTFE) and polyvinylidene fluoride (PVDF) as a catalyst binder; stainless steel mesh (SSM) as a cathode substrate or a cathode itself. Among the tested cathodes, Ni/AC/PTFE obtained the best performance, followed by Ni/AC/PVDF, AC/PVDF, flamed-oxidized SSM (SSM/F) and SSM. Ni/AC/PTFE exhibited the best performance in hydrogen production rate (HPR, 1.88 L/L d), hydrogen purity (97.5%), coulombic efficiency (124%), energy efficiency (216%), cathodic capacitance (0.9924 F), along with the lowest cathodic impedance (35 Ω). The worst performed SSM showed as follows: 0.57 L/L d of HPR, 71% of hydrogen purity, 36% of coulombic efficiency, 62% of energy efficiency, 0.0008 F of cathodic capacitance and 62 Ω of cathodic impedance. This study shows quantitatively the electrochemical and performance transitions of MEC according to the cathode component changes.