Performance of novel GO-Gly/HNTs and GO-GG/HNTs nanocomposites for removal of Pb(II) from water: optimization based on the RSM-CCD model

For the first time, in this study, two novel glycogen-graphene oxide/halloysite nanotubes (GO-Gly/HNTs) and guar gum-graphene oxide/halloysite nanotubes (GO-GG/HNTs) nanocomposites were synthesized as the adsorbents for removal of Pb(II) from water, and the ionic liquid was used in the synthesis as a green solvent. According to the SEM, TEM, EDS, BET, zeta potential, FTIR, and XRD results, GO-Gly/HNTs and GO-GG/HNTs were synthesized successfully. Response surface methodology (RSM) was applied to optimize the experimental conditions. Nanocomposites followed the Langmuir equilibrium model and were best fitted to the pseudo-second-order model. According to the thermodynamic model, the adsorption process was endothermic. Due to several features, these two novel nanocomposites can be considered the proper candidate for Pb(II) removal from water and wastewater. First, these nanocomposites have good adsorption capacity for Pb(II) removal, which is 219 mg/g for GO-Gly/HNTs and 315 mg/g for GO-GG/HNTs. Moreover, nanocomposites can be recycled with proper adsorption capacity after four repeated cycles. These materials can be used to remove Pb(II) from water in the presence of other contaminants because nanocomposites have selective tendency toward Pb(II) in the presence of other pollutants such as Cd2+, Cu2+, Cr2+, and Co2+. In addition, the presence of Ca2+, Mg2+, Na+, and K+ improve Pb(II) removal. Finally, possible mechanisms for each nanocomposite were represented.