Quantification of smelter-derived contributions to thallium contamination in river sediments: Novel insights from thallium isotope evidence.

Thallium(Tl), an extremely toxic metal, is posing great hazards to water safety through anthropogenic activities (e.g., Pb-Zn smelter) and natural weathering in riverine systems. However, the relative contribution from each source remains obscure. This study investigated enrichment pattern of Tl and its isotopic compositions in sediment profiles from a recipient river, which was continuously collecting various Tl-bearing wastes discharged from a large Pb-Zn smelter in South China. Results show that high Tl content and ultra-fine particles (~ μm) of Tl-bearing mineral assemblages, probably derived from Pb-Zn smelting wastes, were ubiquitously observed in both of the depth profiles. In addition, the sediments generally yielded intermediate e205Tl values of -3.76 to 1.01, which resembled those found in smelting wastes. A ternary mixing model was for the first time proposed for quantifying relative Tl contributions from each possible source. The calculation suggests that the smelter wastes are the major contributors, contributing approximately 80% of Tl contamination. All these results indicate that Tl isotope can be used as powerful proxies for quantitatively identifying potential different contributors in the environment. This is of critical importance to further implementation of pollution control and remediation strategy for the riverine systems in the near future.