Amination of cumulated diene hydrocarbons Communication 2. Telomerization of propadiene with allyl amines

1. In the telomerization of propadiene with allyl and diallyl amines in the presence of PdCl2-PPh3-NaBH4 the corresponding conjugated alkadienylamines are formed. Tertiary alkadienylamines form by subsequent conversions of the secondary amines that form first. 2. N-allyl (2,3-dimethylenebutyl)amine, N-diallyl (2,3-dimethylenebutyl)amine, N-allyl bis-(2,3-dimethylenebutyl) amine and their maleic anhydride adducts were synthesized and characterized for the first time.