From Colloidal Monodisperse Nickel Nanoparticles to Well-Defined Ni/Al2O3 Model Catalysts

In the past few decades, advances in colloidal nanoparticle synthesis have created new possibilities for the preparation of supported model catalysts. However, effective removal of surfactants is a prerequisite to evaluate the catalytic properties of these catalysts in any reaction of interest. Here we report on the colloidal preparation of surfactant-free Ni/Al2O3 model catalysts. Monodisperse Ni nanoparticles (NPs) with mean particle size ranging from 4–9 nm were synthesized via thermal decomposition of a zero-valent precursor in the presence of oleic acid. 5 wt % Ni/Al2O3 catalysts were produced by direct deposition of the pre-synthesized NPs on an alumina support, followed by thermal activation (oxidation–reduction cycle) for complete surfactant removal and surface cleaning. Structural and morphological characteristics of the nanoscale catalysts are described in detail following the propagation of the bulk and surface Ni species at the different treatment stages. Powder X-ray diffraction, electron mic...