Nanocellular Foaming Behaviors of Chain-Extended Poly(lactic acid) Induced by Isothermal Crystallization

Recently, the fabrication of semicrystalline polymer foams with a nanocellular structure by supercritical fluids has been becoming a newly developing research hotspot, owing to their peculiar properties and prospective applications. In this work, a facile and effective isothermal crystallization-induced method was proposed to prepare nanocellular semicrystalline poly(lactic acid) (PLA) foams using CO2 as a physical blowing agent. Styrene–acrylonitrile–glycidyl methacrylate (SAG) as a chain extender (CE) was introduced into PLA through a melt-mixing method to improve the crystallization behavior and melt viscoelasticity of PLA. The chain extension reaction between PLA and SAG occurred successfully as well as the branching and micro cross-linking structures were generated in chain-extended PLA (CPLA) samples, which were confirmed by Fourier transform infrared spectra, gel fraction, and intrinsic viscosity measurements. Owing to the nucleation effect of branching points and the restricted movement of PLA mol...