Metal–organic framework-mediated strategy for enhanced methane production on copper nanoparticles in electrochemical CO2 reduction

Abstract Conversion of carbon dioxide (CO 2 ) to useful chemicals is considered a potential solution to resolve the climate threat. In this study, a facile metal-organic framework (MOF)-mediated strategy to obtain an efficient electrocatalyst for the synthesis of methane (CH 4 ) is suggested. Cu-based MOF-74 was chosen as the precursor, which was electrochemically reduced to obtain Cu nanoparticles (NPs). The porous structure of the MOF serves as a template for the synthesis of isolated Cu NP clusters with high catalytic activities and high efficiencies for the CH 4 production in the electrochemical CO 2 reduction reaction. The MOF-derived Cu NPs demonstrate high Faradaic efficiency (>50%) for the CH 4 production with suppressed C 2 production, and 2.3-fold higher methanation activity at −1.3 V (vs. RHE) compared to the commercial Cu NPs.