Fast pyrolysis of torrefied holocellulose for producing long-chain ether precursors in a fluidized bed.

Abstract Combining torrefaction with fast pyrolysis is an achievable route for producing long-chain ether precursors. The results of structural characterization for native and torrefied holocellulose indicated that with increasing torrefaction temperature, the crystallinity index (CrI) decreased slightly and then sharply increased; hydroxyls, O-acetyl branches, ether bond and β-1,4-glycosidic bond were eliminated but carbonyls increased. Maximum mass loss rate and apparent activation energy increased after torrefaction. With an increase in torrefaction temperature, gaseous yield continuously dropped, and liquid product yield climbed to the highest point of 49.04% for holocellulose torrefied at 240 °C (240CS). Torrefaction was unfavorable for the production of small-molecule gases. The bio-oil analysis demonstrated that the yield of acetic acid decreased from 6.35% to 1.43% with torrefaction temperature increasing from 105 °C to 260 °C. Significantly, yields of targeted compounds were dramatically improved after torrefaction, and 240CS afforded the maximum carbon yield of 14.79%.