Stability of 8-hydroxyquinoline aluminum films encapsulated by a single Al2O3 barrier deposited by low temperature atomic layer deposition

2012 
Abstract 100 nm thick 8‐AlQ 3 films deposited onto silicon wafers have been encapsulated by mean of low temperature atomic layer deposition of Al 2 O 3 (20 nm). Investigation of the film evolution under storage test as harsh as 65 °C/85% RH has been investigated up to ~ 1000 h and no severe degradation could be noticed. The results have been compared to raw AlQ 3 films which deteriorate far faster in the same conditions. For that purpose, fluorescence measurements and atomic force microscopy have been used to monitor the film evolution while transmission electron microscopy has been used to image the interface between AlQ 3 and Al 2 O 3 . This concept of bilayer AlQ 3 /Al 2 O 3 barrier films has finally been tested as an encapsulation barrier onto an organic light-emitting diode.
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