On-demand acid-gated fluorescence switch-on in photo-generated nanospheres.
2020
Herein, we introduce a fast, additive-free, ambient temperature photochemical approach – utilising the novel Diels-Alder cycloaddition of a photo-active ortho-methylbenzaldehyde (oMBA) with an asymmetric alkyne – for preparing functional acid-sensitive profluorescent nano-/micro-spheres in one step. Never previously reported, the possibility of applying such a reaction in the context of particle synthesis provides new possibilities for particle design, where multi-step reactivity can be gated into distinct steps. First, a photochemically-gated particle formation step yields a material possessing a reactive, spring-loaded intermediate at every cross-linking point. A second, on-demand step to initiate fluorescence generation subsequently imparts the novel properties of the chemical transformation to the material itself. The synthesised particles are narrow-disperse with an average diameter ranging from 170 – 380 nm.
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