Epoxidation of alkenes by ozone catalysed by Fe(TMP)Cl
2000
Abstract The epoxidation of a number of cyclic and linear terminal alkenes by an O 2 –O 3 mixture at room temperatures catalysed by Fe(TMP)Cl is reported. It appears that the alkene forms a primary ozonide which rearranges to a secondary ozonide, and it is the latter which, when catalysed by Fe(TMP)Cl, affects the subsequent alkene epoxidation. A number of other metal complexes were also tested as catalysts, but Fe(TMP)Cl was the most effective.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
14
References
6
Citations
NaN
KQI