ASYMMETRIC NITROGEN .57. INVESTIGATION OF THE STEREOCHEMISTRY OF AZIRIDINECARBOXYLIC ACID-DERIVATIVES BY NMR

I. I. Chervin,A. A. Fomichev,A. S. Moskalenko,N. L. Zaichenko,Abil E. Aliev,A. V. Prosyanik,V. N. Voznesenskii,R. G. Kostyanovskii

ASYMMETRIC NITROGEN .57. INVESTIGATION OF THE STEREOCHEMISTRY OF AZIRIDINECARBOXYLIC ACID-DERIVATIVES BY NMR

1988

I. I. Chervin
A. A. Fomichev
A. S. Moskalenko
N. L. Zaichenko
Abil E. Aliev
A. V. Prosyanik
V. N. Voznesenskii
R. G. Kostyanovskii

The preferred trans configuration of 1,2-disubstituted aziridines and cis configuration of NH-aziridine-2-carboxylic esters were established by means of the1H and13C NMR spectra and the two-dimensional NOESY and COSY-45 spectra.

Keywords:

Cis–trans isomerism
Nitrogen
NMR spectra database
Two-dimensional nuclear magnetic resonance spectroscopy
Organic chemistry
Stereochemistry
Chemistry
acid derivative
trans configuration

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