Indenocorannulene-Based Materials: Effect of Solid-State Packing and Intermolecular Interactions on Optoelectronic Properties
2017
Curved carbon π-systems, such as indenoorannulenes (2–5) with tunable structural and electronic properties are attractive targets for a new class of active components in molecular devices. The significant curvature of these components favors the formation of columnar stacking in the crystal and confines the electronic states anisotropically on the nanoscale, thus imparting important physical characteristics. Pentaindenocorannulene (C50H20), 5, a deep bowl polynuclear aromatic hydrocarbon, has recently been found to form two polymorphic “solvate” structures, which pack quite differently in the crystalline material and therefore manifest significantly different materials properties. Formation of electronic excitations via excitons is sensitive to the specifics of the packing geometry, such as the degree of π-system overlap, and plays a role in determining the associated optical and transport properties. The present investigation addresses details of the structure and packing of these bowl structures as well...
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