Filter-based differential hygroscopicity analyzer of aerosol particles

We describe a new differential analyzer implementing a technique for studying the hygroscopic properties of filter-precipitated aerosol particles based on a katharometric measurement of the amount of water vapor absorbed by an aerosol sample. The instrument has been tested on particles of sodium chloride and ammonium sulphate. A comparison of our data with the results of analogous measurements described in literature shows that the suggested technique has several important advantages, i.e., (1) higher sensitivity, which allows the measurement of particles of no more than 0.1 mg in mass; (2) a wide range of relative humidity variations (up to 99% at an accuracy of 0.06% RH at the upper-range value); (3) the absence of intermediate measurement steps connected with the need to account for water absorption by elements of a measurement system; and (4) the absence of restrictions to the size and shape of particles studied. In addition, the measurement technique rules out the possibility of errors caused by the kinetic effects of mass transport in the aerosol-water vapor system.