Selective Etching of Silicon from Ti3SiC2 (MAX) To Obtain 2D Titanium Carbide (MXene)

: Until now, MXenes could only be produced from MAX phases containing aluminum, such as Ti3 AlC2 . Here, we report on the synthesis of Ti3 C2 (MXene) through selective etching of silicon from titanium silicon carbide-the most common MAX phase. Liters of colloidal solutions of delaminated Ti3 SiC2 -derived MXene (0.5-1.3 mg mL-1 ) were produced and processed into flexible and electrically conductive films, which show higher oxidation resistance than MXene synthesized from Ti3 AlC2 . This new synthesis method greatly widens the range of precursors for MXene synthesis.