[Trace Carbon Monoxide Detection with a Cavity Ring-Down Spectrometer].
2015
: A cavity ring-down spectrometer (CRDS) was built based on telecom distributed feedback (DFB) diode lasers. The ring down cavity was formed by mirrors of 99. 997% reflectivity with a separation of 130 cm, with an empty ring down time of about 150 µs. A minimum detectable absorption coefficient of 5 x 10(-12) cm(-1) was obtained by averaging about 1,000 recorded spectra. The ring down cavity is thermo-isolated, and used as an interferometer to calibrate the recorded spectrum. A feedback control scheme was applied to step scan the laser frequency, successively matching each of the longitudinal modes of the cavity. By measuring the CO contents in a standard gas sample, the quantitative capability of the CRDS instrument was demonstrated, and a CO detection limit of 4 ppb was achieved. The instrument was applied to monitor the CO concentration in ambient air.
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