Immobilization of silver nanoparticles obtained by electric discharge method on a track membrane surface

Composite poly(ethylene terephthalate) track membranes containing immobilized silver nanoparticles with the aim of using them for surface-enhanced Raman scattering spectroscopy have been obtained and studied. A dispersion of negatively charged silver nanoparticles has been synthesizes by the method of pulsed electrical discharge between silver electrodes immersed in distilled water. To ensure the electrostatic deposition of nanoparticles onto the track membrane surface, it has been modified with polyethyleneimine. The composition and morphology of the surface of the obtained composite membranes have been studied by X-ray photoelectron spectroscopy and scanning electron microscopy. Aggregation of nanoparticles on the surface has been analyzed. The coefficient of Raman-scattering enhancement has been determined by the example of rhodamine 6G molecules adsorbed on a membrane with immobilized silver nanoparticles.