Symmetry-Breaking Synthesis of Multicomponent Nanoparticles

ConspectusMulticomponent nanoparticles (MCNs) composed of disparate inorganic colloidal components have attracted great attention from researchers in both the academic and industrial community, because of their unique properties and diverse applications in energy conversion and storage; heterogeneous catalysis; optics and electronics; and biomedical imaging, diagnosis, and therapy. Compared with single-component nanoparticles (NPs), new or advanced properties of MCNs arise from the synergistic effect between their constituent components and the presence of nanoscale interfaces between distinct materials within the particles. Consequently, the spatial arrangement of nanoscale domains of MCNs becomes equally important in property or function control of MCNs as their size, shape, and composition, if not more. In particular, compositionally asymmetric MCNs may outperform their symmetric counterparts in many of their applications. To this end, the seed-mediated growth (SMG) method, which involves depositing a ...