Functional nanoparticle reinforced starch-based adhesive emulsion: Toward robust stability and high bonding performance.

Abstract Sustainable bio-based adhesive is a promising substitute for petroleum-based adhesives to alleviate serious environmental and health problems. In this work, a nanoengineered starch-based adhesive was fabricated by grafting vinyl acetate (VAc) onto starch molecule and subsequently incorporating the functional nanoparticle [TiO2-coupling-poly(butyl acrylate, BA), TKB] to overcome the drawbacks present in conventional nanocomposite adhesive. Results showed that the presence of BA altered the surface property of TKB, leading to improved dispersion. In the adhesive with 4% (mass ratio to starch) TKB, TKB aggregates played the role as a sliding bridge, which significantly promoted the storage stability and shear strength in both dry and wet states. Additionally, the latex film with 4% TKB exhibited high compatibility and water resistance due to the promoted hydrophobicity. This study provides a fundamental insight into the improvement of functional nanoparticles on the performance of starch-based adhesive, suggesting a novel strategy for designing high-performance bio-adhesive.