Design of Hetero-Nanostructures on MoS2 Nanosheets To Boost NO2 Room-Temperature Sensing

Molybdenum disulfide (MoS2), as a promising gas-sensing material, has gained intense interest because of its large surface-to-volume ratio, air stability, and various active sites for functionalization. However, MoS2-based gas sensors still suffer from low sensitivity, slow response, and weak recovery at room temperature, especially for NO2. Fabrication of heterostructures may be an effective way to modulate the intrinsic electronic properties of MoS2 nanosheets (NSs), thereby achieving high sensitivity and excellent recovery properties. In this work, we design a novel p–n hetero-nanostructure on MoS2 NSs using interface engineering via a simple wet chemical method. After surface modification with zinc oxide nanoparticles (ZnO NPs), the MoS2/ZnO hetero-nanostructure is endowed with an excellent response (5 ppm nitrogen dioxide, 3050%), which is 11 times greater than that of pure MoS2 NSs. To the best of our knowledge, such a response value is much higher than the response values reported for MoS2 gas sens...