Pd-Initiated Polymerization of Dendron-Containing Diazoacetates to Afford Dendronized Poly(substituted methylene)s with Narrow Molecular Weight Distribution and Its Application to Synthesis of pH-Responsive Dendronized Polymers

Hiroaki Shimomoto,Ryo Hohsaki,Daisuke Hiramatsu,Tomomichi Itoh,Eiji Ihara

Pd-Initiated Polymerization of Dendron-Containing Diazoacetates to Afford Dendronized Poly(substituted methylene)s with Narrow Molecular Weight Distribution and Its Application to Synthesis of pH-Responsive Dendronized Polymers

2020

Hiroaki Shimomoto
Ryo Hohsaki
Daisuke Hiramatsu
Tomomichi Itoh
Eiji Ihara

A variety of benzyl ether-type dendron units were introduced as an ester substituent of diazoacetates, and their Pd-initiated polymerization behavior was investigated in detail. Because of the ster...

Keywords:

Dendrimer
Methylene
Chemistry
Molar mass distribution
Polymer
Polymerization
Organic chemistry

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