Stratospheric ozone changes from explosive tropical volcanoes: Modelling and ice core constraints

Major tropical volcanic eruptions have emitted large quantities of stratospheric sulphate and are potential sources of stratospheric chlorine although this is less well constrained by observations. This study combines model and ice core analysis to investigate past changes in total column ozone. Historic eruptions are a good analogue for future eruptions as stratospheric chlorine levels have been decreasing since the year 2000. We perturb the pre-industrial atmosphere of a chemistry-climate model with high and low emissions of sulphate and chlorine. The sign of the resulting Antarctic ozone change is highly sensitive to the background stratospheric chlorine loading. In the first year, the response is dynamical, with ozone increases over Antarctica. In the high HCl (10 Tg emission) experiment, the injected chlorine is slowly transported to the polar regions with subsequent chemical ozone depletion. These model results are then compared to measurements of the stable nitrogen isotopic ratio, δ15N(NO&mi...