Direct conversion of CO2 to a jet fuel over CoFe alloy catalysts

ABSTRACT The direct conversion of carbon dioxide (CO2) using green hydrogen is a sustainable approach towards jet fuel production. However, achieving a high level of performance remains a formidable challenge due to the inertness of CO2 and its low activity towards subsequent C–C bond formation. In this study, we prepared an Na modified CoFe alloy catalyst using layered double hydroxide precursors that directly transforms CO2 to a jet fuel composed of C8–C16 jet fuel range hydrocarbons with very high selectivity. At a temperature of 240 oC and pressure of 3 MPa, the catalyst achieves an unprecedentedly high C8–C16 selectivity of 63.5% with 10.2% CO2 conversion and a low combined selectivity of less than 22% towards undesired CO and CH4. Spectroscopic and computational studies show that the promotion of the coupling reaction between the carbon species and inhibition of the undesired CO2 methanation occurs mainly due to the utilisation of the CoFe alloy structure and addition of the Na promoter. This study provides a viable technique for the highly selective synthesis of eco-friendly and carbon-neutral jet fuel from CO2.