Synthesis and properties of novel cluster phases. Progress report

Research on cluster compounds this period (past periods covered such compounds such as NbMTe{sub 2}, TaFe{sub 1.25}Te{sub 3}, Nb{sub 3}SiTe{sub 6}, etc.) was concentrated on LiMo{sub 3}Se{sub 3}. A LiMo{sub 3}Se{sub 3} bundle {approximately} 70 nm wide was grown on a holey carbon substrate; STEM was used to resolve individual 6 {angstrom} wires, and the Mo{sub 3}Se{sub 3} flat ``monomer`` units is resolved at 2.3 {angstrom} (Mo atoms wrapped in Se atoms). Inorganic-organic polymer composites are being studied; conducting films have been prepared. The sheet structure of Nb{sub 3}SiTe{sub 6} is shown. 4 figs. (DLC)