Enhancing the performance of P3HT:ICBA based polymer solar cells using LiF as electron collecting buffer layer and UV–ozone treated MoO3 as hole collecting buffer layer

Abstract Efficient bulk-heterojunction (BHJ) polymer solar cells (PSCs) based on poly (3-hexylthiophene) (P3HT): indene-C 60 bisadduct (ICBA) were fabricated with lithium fluoride (LiF) as electron collecting buffer layer and UV–ozone (UVO) treated molybdenum trioxide (MoO 3 ) as hole collecting buffer layer. LiF is observed to be critical for the device performance, significantly enhancing the fill factor (FF) and the efficiency compared to the device without LiF layer. MoO 3 layer is also critical to the device performance, efficiently extracting holes to prevent the exciton quenching and reducing the interfacial resistance because of alignment of energy band. After UVO treatment on MoO 3 film, its surface morphology, transmittance and film quality can be improved, therefore, it is beneficial to the performance of the PSCs. The optimal thickness of MoO 3 and UVO treatment time on MoO 3 was 12 nm and 15 min, respectively. Based on these optimal parameters, a power conversion efficiency (PCE) of 6.43% was obtained under AM1.5G 100 mW/cm 2 illumination.