Low temperature magnetic structure of the quasi 1-dimensional magnet Ni2SiO4
2009
Ni2SiO4, Liebenbergite, is an example of a quasi-one-dimensional magnet made up of frustrated corner sharing triangles of Ni2+ (S = 1) ions that propagate parallel to the b axis. Ni2SiO4 is isostructural with olivine, a common mineral of varying composition Fe2-xMgxSiO4, and is described in the orthorhombic space group Pnma. A synthetic polycrystalline sample of Ni2SiO4 was studied using powder neutron diffraction with spectra taken above and below the antiferromagnetic ordering transition (TN ≈ 34 K). Analysis of the magnetic structure was carried out using the symmetry models of corepresentation theory. The refined spin structure evidences both ferromagnetic and antiferromagnetic inter-chain interactions, and ferromagnetic intra-chain coupling. The competition between the magnetic interactions can be seen in the canting of the moments away from a collinear arrangement.
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