Controlled synthesis of rh-In2O3 nanostructures with different morphologies for efficient photocatalytic degradation of oxytetracycline

2019 
Abstract Two rhombohedral corundum-type In 2 O 3 (rh-In 2 O 3 ) nanostructures were successfully prepared through solvothermal synthesis of InOOH precursors combined with post-annealing treatment. One is a unique and monodisperse urchin-like rh-In 2 O 3 with three dimensional structures; another is a small size rod-like rh-In 2 O 3 with two dimensional nanostructures. The morphological difference of the two InOOH precursors was mainly controlled by sodium dodecyl sulfonate (SDS) which acted as a soft template during the synthesis. The measurements of X-ray photoelectron spectroscopy, nitrogen adsorption and optical absorption indicated that the both obtained rh-In 2 O 3 nanostructures are mesoporous materials which may possess oxygen vacancies and narrower band gaps. The photocatalytic activities of as-prepared urchin-like and rod-like rh-In 2 O 3 were investigated by degrading oxytetracycline (OTC) under ultraviolet light irradiation. Compared with a commercial In 2 O 3 , the two above rh-In 2 O 3 nanostructures exhibited an absolute superiority on photo-degrading OTC. Furthermore, the probable photocatalytic reaction mechanism was discussed and proposed according to radical trapping experiment and the detection of degradation intermediates.
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