Ti2C MXene Modified with Ceramic Oxide and Noble Metal Nanoparticles: Synthesis, Morphostructural Properties, and High Photocatalytic Activity

2019 
Among two-dimensional (2D) materials, such as graphene, a new family of 2D anisotropic carbides and nitrides of early transition metals (MXenes) is very interesting because of the potential applications in electronics, medicine, and photocatalysis. In this paper, preparation, morphostructural characterization, band gaps determination, and salicylic acid photodegradation ability of Ti2C MXene and six nanocomposites consisting of the MXene modified by TiO2, Ag2O, Ag, PdO, Pd, and Au are reported. It was confirmed using electron diffraction studies, energy dispersive X-ray spectroscopy, and high-resolution transmission microscopy that metals and metal oxides occur on the MXene flakes as nanoparticles in a shape of spots. The band gaps determined experimentally using Tauc’s method are placed in the region of 0.90–1.31 eV. In recent years, the method of photocatalytic decomposition of pollutants using semiconductor photocatalysts and UV–vis energy has become increasingly important. The MXene based nanocomposit...
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