The side effects of nitrification inhibitors on leaching water and soil salinization in a field experiment

In experiments carried out in greenhouses, some authors have shown that ammonium sulphate induces greater soil acidity and salinity than other sources of N. Moreover, nitrif ication inhibitors (NI) tend to cause ammonium to accumulate in soil by retarding its oxidation to nitrate. This accumulated ammonium would also have an effect on soil salinity. Consequently, the aim of this paper was to evaluate the soil and leaching water salinization effects associated with adding NI, dicyandiamide (DCD) and dimethylpyrazole-phosphate (DMPP) to ammonium sulphate nitrate (ASN) fertilizer. This experiment was carried out in the field with an irrigated maize crop. Drainage and Na concentration were measured during both seasons (2006 and 2007) and leached Na was determined. The treatments with NI (DCD and DMPP) were associated with greater Na concentrations in soil solutions and consequently higher rates of Na leaching (in 2007, ASN-DCD 1,292 kg Na ha ‐1 , ASN-DMPP 1,019 kg Na ha ‐1 ). A treatment involving only ASN also increased the Na concentration in soil and the amount of Na leached in relation to the Control (in 2007, ASN 928 kg Na ha ‐1 and Control 587 kg Na ha ‐1 ). The increase in the ammonium concentration in the soil due to the NI treatments could have been the result of the displacement of Na ions from the soil exchange complex through a process which finally led to an increase in soil salinity. Treatments including ammonium fertilizer formulated with NI produced a greater degree of soil salinization due to the presence of ammonium from the fertilizer and accumulated ammonium from the nitrification inhibition.