Layered double hydroxide based materials applied in persulfate based advanced oxidation processes: property, mechanism, application and perspectives

Abstract Recently, persulfate-based advanced oxidation processes (persulfate-AOPs) are booming rapidly due to their promising potential in treating refractory contaminants. As a type of popular two-dimensional material, layered double hydroxides (LDHs) are widely used in energy conversion, medicine, environment remediation and other fields for the advantages of high specific surface area (SSA), good tunability, biocompatibility and facile fabrication. These excellent physicochemical characteristics may enable LDH-based materials to be promising catalysts in persulfate-AOPs. In this work, we make a summary of LDHs and their composites in persulfate-AOPs from different aspects. Firstly, we introduce different structure and important properties of LDH-based materials briefly. Secondly, various LDH-based materials are classified according to the type of foreign materials (metal or carbonaceous materials, mainly). Latterly, we discuss the mechanisms of persulfate activation (including radical pathway and nonradical pathway) by these catalysts in detail, which involve (i) bimetallic synergism for radical generation, (ii) the role of carbonaceous materials in radical generation, (iii) singlet oxygen (1O2) production and several special nonradical mechanisms. In addition, the catalytic performance of LDH-based catalysts for contaminants are also summarized. Finally, challenges and future prospects of LDH-based composites in environmental remediation are proposed. We expect this review could bring new insights for the development of LDH-based catalyst and exploration of reaction mechanism.