Lewis-acid catalysed arylation of the hydroxyamino sugar moiety of the natural product SB-219383
2001
The natural product SB-219383 1a contains an unique bicyclic hydroxyamino sugar moiety. Novel C-glycosidation reactions of this hydroxyamino sugar moiety are reported. The formation of a sugar nitrone intermediate is postulated which is subsequently trapped by electron-rich aromatic rings to yield C-aryl hydroxyamino sugars.
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