Enhancement of the gas sensing performance of carbon nanotube networked films based on their electrophoretic functionalization with gold nanoparticles

Controlled amounts of colloidal Au nanoparticles (NPs), electrochemically pre-synthesized, were directly deposited on MWCNTs sensor devices by electrophoresis. Pristine and Au-functionalized MWCNT networked films were tested as active layers in resistive gas sensors for detection of pollutant gases. Au-modified CNT-chemiresistor demonstrated higher sensitivity to NO 2 detecting up to sub-ppm level compared to pristine one. The investigation of the cross-sensitivity towards other pollutant gases revealed the decrease of the sensitivity to NO 2 with the increase of Au content, and, on the other side, the increase of that to H 2 S; therefore the fine tune of the metal loading on CNTs has allowed to control not only the gas sensitivity but also the selectivity towards a specific gaseous analyte. Finally, the sensing properties of Au-decorated CNT sensor seem to be promising in environmental and automotive gas sensing applications, based on low power consumption and moderate operating temperature.