Synthesis and enhanced gas sensing properties of flower-like SnO2 hierarchical structures decorated with discrete ZnO nanoparticles
2014
Abstract Flower-like ZnO/SnO 2 hierarchical structures with different ZnO contents were successfully prepared via a flexible two-step synthesis method, in which nanosheets-assembled flower-like SnO microstructures were prepared in advance through a solvothermal method, and then were used as sacrificial templates to prepare ZnO/SnO 2 composites by annealing with Zn(CH 3 COO) 2 ⋅2H 2 O. Through the annealing process, the as-prepared flower-like SnO was oxidized to SnO 2 without changing the morphology, and ZnO nanoparticles (NPs) with the size about 10–50 nm were simultaneously decorated on the surface of sheet-like SnO 2 petals. The dispersion of ZnO NPs was found to have a close relationship with the ZnO content of ZnO/SnO 2 composite. The gas sensing properties of the prepared ZnO/SnO 2 composites with different ZnO contents were investigated. The composite with 10 wt.% ZnO exhibits remarkably higher sensitivity to ethanol than the pure SnO 2 and the composites with 5 wt.% and 15 wt.% ZnO contents. The influences of ZnO NPs and ZnO/SnO 2 heterojunctions on the gas sensing properties of ZnO/SnO 2 composites were discussed.
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