Hydrogen-bonded structure and mechanical chiral response of a silver nanoparticle superlattice

Self-assembled nanoparticle superlattices, which consist of inorganic cores capped by organic ligands, can show emergent behaviour as a result of the coupling between their nanoscale components. The atom-level structure of a silver nanoparticle superlattice, deduced from X-ray imaging and simulations, is now reported as well as its response to hydrostatic compression, which involves anomalous pressure softening and correlated chiral rotation of the nanoparticles.